The band signed to Hollywood Records in 2001 after the success of an independently-released, self-titled EP, which sold all 2,000 copies that were manufactured. Hollywood Records released their full-length, major-label debut, Saturate, on August 27, 2002. The album peaked at number 2 on the Billboard Top Heatseekers Chart and at 136 on the Billboard Top 200.

The album's first single, "Polyamorous", received a fair amount of radio play, although it failed to reach mainstream audiences. A video was released in two different versions for Polyamorous: one that had all live-action footage, and one that had footage of the video game Run Like Hell. The song was also used for the video games WWE Day of Reckoning, WWE Smackdown vs. Raw, and WWE Wrestlemania 21. In addition The song was played during an episode of the TV show "8 Simple Rules."

The second single "Skin" was also released from Saturate, although it fared worse than "Polyamorous" and received even less airplay."Skin" was also performed live on several talk shows including "Last Call: With Carson Daly," "The Late Late Show With Craig Kilborn" and "Jimmy Kimmel Live." In an interesting note, singer Burnley has been known to state his disdain for the song during live performances and has the crowd sing the words as the band plays.

"Medicate" was also released as the third and final single, to little commercial success and airplay.

"Wish I May" the first track off of the album was played during the end credits of the horror film "Wrong Turn."

At live performances, Breaking Benjamin often plays a brief sound clip of the Wicked Witch of the West prior to playing the track "Home", which has its lyrics largely influenced by The Wizard of Oz (1939 film).

The band was planning on releasing a studio version of their cover of "Enjoy the Silence" along with "Ladybug" on the European version of Saturate. However, the European version was never released. "Ladybug" was eventually released on the "So Cold" EP.

Saturate has gone on to sell over 300,000 copies making it a moderate success.

Breaking Benjamin released their second album, We Are Not Alone, on June 29, 2004. The album featured the lead off single "So Cold", which reached number two on the United States Billboard Mainstream Rock chart. The promotional wheel was put behind the track as the band performed live on various talk shows such as "Late Night with Conan O'Brien," "Last Call with Carson Daly," and "Jimmy Kimmel Live." The song has a lengthy history as the band had written 2 other songs before they were finally combined to become "So Cold". The first was "Inertia", then "Always". Both were never released, but have been played live. The live versions can be found on the internet. The band had two music videos made for "So Cold." one of which was a promotional video made for the movie Hellboy. So Cold", spent 37 weeks in the top 20 of the Billboard charts (as of February 3, 2005). The commercial success of "So Cold" led to We Are Not Alone debuting at number 20 on the Billboard 200 selling 48,000 copies and achieving platinum status in late 2005.

Also released as singles from the album were "Sooner or Later" and a re- recorded version of "Rain", which was featured on later pressings of the album. "Sooner or Later", had a video created for it and got a fair amount of radio play reaching number two on the Mainstream Rock Charts. The track was also featured during an episode of the tv show "Summerland" and performed live on "The Tonight Show with Jay Leno."

During a tour in support of "We Are Not Alone" Aaron Fink's father joined the band on tour, whose music collection is what originally sparked Aaron's interest in music. Gary Fincke is a professor at Susquehanna University and wrote Amp'd: A Father's Backstage Pass about his travels with the band. Johan Hegg did backing Vocals in the song "So Cold".

The track "Breakdown" was featured in a commercial for the ABC Family movie The Hollow."

The track "Forget It" was featured on an episode of the tv show "Smallville," during a scene in the movie "American Pie Presents: Band Camp," and during the end credits of "National Treasure."

The band never travels outside of the U.S. and Canada due to Ben Burnley's fear of flying (though he said he would love to play outside the States and will go as far as a boat will take him). This is referenced in the song "Break My Fall."

In September of 2004, drummer, and founding member of Breaking Benjamin, Jeremy Hummel was relieved of his duties in the band. Subsequently, on September 28, 2005, Hummel filed a federal lawsuit against the remaining members of Breaking Benjamin, as well as its management, claiming he was not paid for songs he helped write. Hummel's lawsuit asked for more than $8 million in damages. A message was released October 25, 2006 on the band's official website stating that the band and Hummel had come to agreement on the lawsuit.

The album was recorded at The Barbershop Studios in Hopatcong, New Jersey. It was released on August 8, 2006 and quickly sold out at major retail chains such as Best Buy and Target. The album sold 131,000 copies in its first week, which made it the fastest selling and highest charting Breaking Benjamin album to date, hitting #2 on the US Billboard Top 200.

The first single "The Diary of Jane" was featured in the video game NASCAR 07, was also used in a commercial for the FOX television show Bones, and was used in the Portuguese TV show Vingança.

In the fall of 2006 the band began a tour opening for Godsmack for the IV tour, hitting up mostly eastern and Ohio Valley venues, and soon moving out west, still in support of the Phobia album. Several of the shows had been canceled, or turned into Breaking Benjamin headliners due to scheduling conflicts. Many of Breaking Benjamin's tour dates from December 3rd have been rescheduled due to illness in the band's ranks. All dates were rescheduled as the band announced another headlining leg before going on a nationwide tour with Three Days Grace and Nickelback.

On March 4, 2007, HDNet premiered a one-hour show of the Breaking Benjamin concert in Bethlehem, Pennsylvania at Stabler Arena. This is also the concert that was included on the Phobia re-release DVD in April of 2007, advertised as "The Homecoming". Footage of the band's live Stabler Arena performance of "Breath" comprises the song's music video[1].

On April 17, 2007, Breaking Benjamin re-released the album Phobia. The album featured a DVD with about an hour of their Stabler Arena concert footage.

The band recently obtained their first number 1 billboard single with "Breath".

They completed a co-headlining tour in the United States with Three Days Grace and had Red and Puddle of Mudd as openers.

The album reentered the Billboard 100 at number 38 on May 5, 2007 with its reissue.

On June 29, 2007, the band appeared on Jay Leno and they performed "Breath". On July 6, 2007, the band performed "Breath" again on Craig Ferguson.

The band did not perform as scheduled on July 9, 2007 at the Tabernacle in Atlanta due to an illness that Ben had. Angry fans reportedly threw refreshments at the road crew, hitting one in the head with a full water bottle. No injuries, however, were reported.[citation needed]

Two other concerts wrapping up their tour (in Myrtle Beach, SC on July 10 and Greensboro, NC on July 11) were canceled as well. On their website, they announced that Burnley was ill and unable to perform in Atlanta and at the two remaining shows. Rumors that the band was breaking up turned out to be false, as the band announced a 36-date fall 2007 tour with Three Days Grace, Seether, Skillet (first half) and Red (second half).